12/16/2023 0 Comments The magic circle achievement guide![]()
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12/16/2023 0 Comments Orbital diagrams for all elements![]() ![]() The next two electrons will go into the 3s orbital, and after that, the remaining four electrons will go into the 3p orbital.The next two electrons will go into the 2s orbital, after that, the next 6 electrons will go into the 2p orbital since the p subshell can hold up to 6 electrons.Now, for the electron configuration of Sulfur, the first 2 electrons will go in 1s orbital since s subshell can hold a maximum of 2 electrons.As per the Aufbau rule, the electrons will be filled into 1s orbital first then 2s, then 2p…so on.A Sulfur atom is a neutral atom that has an atomic number of 16 which implies it has a total of 16 electrons.Sulfur Electron configuration using the Aufbau Principle So, the order in which the orbitals are filled with electrons from lower energy to higher energy is – 1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p < 6s < 4f < 5d < 6p < 7s < 5f < 6d < 7p and so on. Therefore, we have a diagonal rule for electron filling order in the different subshells using the Aufbau principle. So, all these are basics of How filling of electrons will be done in different subshells, obviously, you don’t have so much time for writing electron configuration by using so many rules. ⇒ For two different subshells having same (n + l) value, then the subshell with lower value of n has lower energy. ⇒ Lower the value of (n + l) for an subshell, the lower its energy, hence, it will be filled first with electrons. Generally, (n + l) rule is used to predict the energy level of subshells. Now, the electron configuration of an atom can be built by filling the electrons in a lower energy subshell first then higher, higher, and higher. So, in short, the s subshell can hold a maximum of 2 electrons(1 orbital), the p subshell can hold 6 electrons(3 orbitals), the d subshell can hold 10 electrons(5 orbitals), and the f subshell can hold at most 14 electrons(7 orbitals). These subshells can hold a maximum number of electrons on the basis of a formula, 2(2l + 1) where ‘l’ is the azimuthal quantum number. Simply understand that there are commonly four different types of subshells – s, p, d, and, f. For example, the 1s orbital will be filled first with electrons before the 2s orbital.In short, the electrons will be filled in the orbital in order of their increasing energies. It states that the orbital with the lowest energy level will be filled first before those with high energy levels.The Aufbau rule simply gives the order of electrons filling in the orbital of an atom in its ground state.The word ‘Aufbau’ in German means ‘building up’. 12/16/2023 0 Comments Trine 2 hidden charactersThe Knight is the best pick for close combat but has limited platforming skill. The Knight is the most straight forward of the three, able to block attacks and fireballs with his shield, swipe with his sword, and throw a massive hammer at distant targets. Aside from the narration during the loading screens, there's only infrequent character quips in-game, so don’t approach these games looking for a narrative-heavy adventure. ![]() The three (at the time unnamed) protagonists - each of which have their own appraoch to platforming and combat - are bound to the Trine artefact and sent on a quest to recover three fragments, then defeat an undead king and his army, and finally restore peace to the land. Presentation aside (something that is much improved in the Enchanted Edition), the real draw is the simple yet engaging puzzling and platforming mechanics, which rely on an entertaining blend of physics, speed, creativity, and coordination. Retro-style games were making a comeback but this 2.5D indie puzzle-platformer sported 3-player local-coop, gorgeous visuals that could compete with contemporary “AAA” titles, and it had an enchanting soundtrack from Ari Pulkkinen to boot. 2009, was developed and released by Frozenbyte with little fanfare, yet quickly picked up a sizeable audience. This weekly post aims to highlight some of those games we’ve got around to playing but never got around to reviewing. Unfortunately, that often means far too many good indie titles fly under the radar without the recognition they deserve. Simply keeping on top of the steady release of “AAA” game is challenging enough these days, with a larger market than ever before, and a massive number of devs and publishers trying to sate that demand. 12/15/2023 0 Comments Omnigraffle ipadIf you need to create eye-popping charts quickly, and you don’t have too much data to plot, OmniGraphSketcher works wonders, and it’s mostly a delight to use.The OmniGraffle mind-mapping iPad app has been downloaded over 5,000 times since it launched the day the iPad came out (April 3), and at a whopping $49.99 per download that’s $250,000 total in one month (minus Apple’s cut of course). ![]() The palette would occasionally vanish less than a full second after I’d first tapped to open it. The other annoyance was that the info palette sometimes chose to disappear on its own, even while I was in the middle of using it. Skinner Box, since I was never quite sure what I’d done to finally make the keyboard appear. I’d tap, double tap, tap and hold-it felt like a On occasion, I found it difficult to enter text-entry mode when creating or editing labels. I ran into two glitches that marred my overall experience with the app slightly. You can add fills to various sections, change the chart’s type, add or remove data points, and, of course, mix and match all the options to create something incredibly visually compelling-or awful, depending on your skill level. OmniGraphSketcher doesn’t offer any direct way to create a legend for your graph instead, you’ll need to label each line individually, or create your own legend using the in-app tools.Īdjusting other elements of your graph is also impressively simple. In fact, there’s a surprising amount of control for every element of your chart-with one notable exception. You can add labels simply by double-tapping anywhere on the screen. You can also control whether individual data points are plotted along the line or not. You can adjust line thickness, patterns, and colors. Single-tapping on an object lets you tap the info button to make tweaks. ![]() OmniGraphSketcher automatically smoothes out your hand-drawn lines quite pleasantly. You can choose to tap individual data points, or trace a line across them. You can literally create a chart in minutes: You double tap the numbers along the axes to set the minimums and maximums, and the app fills in the rest. With a simpler focus than OmniGraffle’s, OmniGraphSketcher is easier to learn. Once you’ve done that, adjusting colors and thickness is a snap. What’s My Line: Creating charts in OmniGraphSketcher is as simple as tracing the lines of data. Like OmniGraffle, OmniGraphSketcher offers a document-based tutorial that introduces you to the app’s key features. ![]() The app can’t import any numeric data you have rather, when you create your graphs, you’ll need to enter all the data points manually. Again, it’s doable, but requires some patience and a learning curve. But a lot of functionality hides behind several taps. I learned a few shortcuts in OmniGraffle without even trying I noted that tapping with three fingers immediately pasted whatever I’d copied without needing to trigger the normal paste menu first. It works fine if you have just a few objects, but becomes unmanageable fast. In OmniGraffle for iPad, that functionality is there, but it’s presented in a unique way: You tap the layers button, and then edit to drag and rearrange the ordering of various objects. Even once you’ve mastered the technique, it’s still a bit clunky: Once you add an object in draw mode, you have to tap “Done” at the top of the screen before you can re-enter the main editing mode, which never feels entirely obvious.Īs I worked with more complicated layouts, I started searching for the “send to back” functionality I needed to arrange objects when they overlapped. But to draw your own shapes, you first need to enter the drawing mode, which itself can toggle between a predefined shape mode or a freehand mode. You can use many built-in stencils by dragging and dropping. Taking Shape: You can create new shapes in OmniGraffle by hand or by choosing from built-in stencils across several categories.Ĭreating objects can be slightly more complex. 12/15/2023 0 Comments Kasino club stanleyLocated at the headwaters of the Salmon River, Redfish Lake is perfect for kayaking with smooth water …Īaaah-inspiring scenery (so long as your paddling partner doesn’t block the view) …īesides the hiking at Redfish Lake, the Iron Creek trail to Alpine Lake and Sawtooth Lake is also spectacular, though difficult. ![]() ![]() The sparkling-clear waters of Redfish Lake were the clearest we’ve ever seen anywhere, including the glacier-fed lakes along the Icefields Parkway of Canada. The more-accessible Redfish Lake, 15 miles south of town, and its lodge, marina, boat rentals, restaurant and multiple campgrounds are one of the main hubs of the action.įrom here, you (and your dog!) can take a short boat ride in a very small boat across the lake to some awesome hiking trails overlooking the lake.Ĭatch the boat back to the Marina when you are done exploring, or if you’re ambitious (not us, not anymore) you can do a challenging 14-mile hike all the way back instead. Stanley is situated at the base of the Sawtooth Mountains.Ĭan there be any wonder why they are called the Sawtooths?Įven though Stanley’s population is only 63, it swells into the tens of thousands during the summer, as travelers come for the beauty and the outdoor recreation, including high-altitude hikes to Alpine Lake, Sawtooth Lake, and the Bench Lakes. When the wind would blow just right and clear it out , however, the views were spectacular! Unfortunately, like most of the West, right now it’s frequently filled with wildfire smoke. ![]() Stanley and Salmon are two of our favorite small towns in central Idaho … really small! Current CDC guidelines probably let more people than their entire populations into your favorite restaurant! Well helllllooooo, Stanley, Idaho! We love your low valleys, soaring peaks, lush farmland, outdoorsy people and totally kick-back attitudes! 12/15/2023 0 Comments Macx video converter pro pal to ntcs![]() Click the button to extract DVD to digital files.įor example, if you want to rip a scene from a dvd, you can trim the movie into several parts then rip it. Or you can just choose MP3 to Convert DVD as audios. For edit and enhance the DVD to iMovie, you can choose Apple Software > iMovie.ģ. For storing you DVD a USB, you just choose HEVC MP4, which will give you the best result.Ģ. It will be 45% smaller size at almost the same quality.ġ. If you want to get a good quality MP4 with the good output quality and smaller file size, convert DVD to HEVC MP4. And the batch processing support helps you convert DVD to MP4 in a very short time.Īs for a professional DVD to MP4 converter for Mac, all popular formats are well categorized by terminal devices. You can add your home movies, encrypted DVDs, or PAL DVDs, karaoke DVDs, NTSC DVDs, old DVDs, etc. Go to the first one, which can convert videos, rip DVDs and download online videos. You will see a simple interface with three tabs. After installation, open Cisdem Video Converter. Steps to Convert DVD to MP4 on Mac via Video Converter: You can try it on your Mac with one click and download. It offers a free trial version for all Mac users. Support macOS 10.12 or later, including Sierra, High Sierra, Mojave, Catalina, Big Sur, Monterey, and Ventura.Download free videos from YouTube, Myspace, LinkedIn, and other 1000+ sites.Crop/trim DVD videos and add effects/watermarks to them before digitalizing.Change the video resolution, audio & video codec, frame rate, etc.Batch convert DVDs and other media files with fast speed.Remove DVD copy protection like Region Code, CSS, Disney X-Project, etc.Support any input DVD disc and DVD folder.Convert DVD to MP4, M4V, WMV, MP3, iPhone, iPad, Samsung, Nokia, HTC, iTunes, TV, blackberry, etc.We noticed no difference of the quality, really a 1:1 copy of the original DVD and size are also much smaller. What impress us most is that this app gives a very good quality output MP4, We inspected the output MP4 by this program and compared it to the source video. You can also add DVD Folder or ISO file and convert it to MP4. Apart from conversion capabilities, it also allows you to download online videos, trim to convert certain part of DVD, combine multiple video clips, edit videos, etc. DVDs, 99-title DVD, old DVDs, etc.) to MP4, MPEG, MKV, AVI, WMV, MOV, FLV, MP3, FLAC, iPhone, iPad, Android, Xbox, PS3/4/5 etc. You can use it to rip unprotected and protected DVDs (Regional DVDs, Disney/Paramount etc. Latest version: 7.2.0 released in March 24, 2022Ĭisdem Video Converter it’s an excellent toolbox that helps you convert DVD, audio, video files to more than 300+ formats. How to Convert DVD to MP4 on Mac? #1 Cisdem Video Converter - Convert DVD to MP4 with Good Balance Between Quality and Size You are not able to store the DVD video on Mac or other PC as backup or copy.There is an exception to the public performance rights that allows non-profit, educational institutions the right to publicly perform videos/DVDs for non-profit, educational purposes. Some videos/ DVDs labeled "Home Use Only?" Vendors or publishers want to remind consumers that videos and DVDs should not be shown to the public as this is an exclusive right of the rights holder.If you want to play a DVD video on a DVD player, you need to prepare the DVD drive that supports your DVD type (CD-R, CD-RW, DVD-R, DVD-R DL, DVD+R, DVD+R DL, DVD-RW, DVD+RW, DVD-RAM, BD-R, or BD-RE).What's DVD Video Limited in / RestrictionĭVD video offers high quality and clear visual clarity, but it has some restrictions that you should pay attention to. We provide the detailed using steps of each app, hope this can help you find the right tool and digitize all you DVD collections easily. In this article we test and rated the best DVD to MP4 converters for Mac on the market. ![]() And for most of the commercial movies you have to deal with copy protection. Some DVD ripper takes very long time to rip a DVD, Some may rip really fast but the output MP4 file size is gigantic and the output quality may merely come as 480p. We know it’s hard to find a good DVD to MP4 converter, for Mac users it’s even harder. But now they are gathering dust on a shelf, it’s time to to digitize your DVD collection, and convert DVD to MP4 is the ideal way. This are your favorite movies or cherished personal footages. You’ve spent a lot of money and time on your DVD library. 12/15/2023 0 Comments Greenbooks jrr tolkien ww1![]() He graced the cover of Time magazine in 1947. In the 1940s, The Screwtape Letters were a best-seller and their BBC broadcast made Lewis a household name. His sermons were entertaining and well-attended. “How is your hobbit?” Tolkien’s colleagues reportedly mocked.įor Lewis, his extra-curricular activities were more widely accepted. He could find respectability as a frumpy Oxford don and Anglo Saxon expert, but harboring second life telling stories of wizards, dragons, and rings of power was barely tolerable, even if the books sold well. But the publication of The Hobbit in 1937 and The Lord of the Ringsin 19 clashed with his academic reputation. His groundbreaking essay on Beowulf and his definitive translation of Sir Gawain and the Green Knight cemented his scholarly status. Only the faintest traces of his days here remain etched in the silhouettes of the eight Oxford homes and four colleges associated with his studies and scholarship.Īmong his colleagues, Tolkien was somewhat of an oddball. Even today, both town and university remain uncertain how to remember Tolkien’s contribution to letters. Yet the same institution never fully adopted its other reclusive literary anomaly. When “Jack” Lewis, as Lewis was known, began to publish in the 1930s and 1940s and lecture on Christian topics, Oxford quickly embraced him as a literary and religious celebrity. ![]() They lost themselves in anachronistic tales and created make-believe places - engaging in what today we might disparagingly call “escapism.” Of course, the realms of Lewis’ Narnia and Tolkien’s Middle-earth are fraught with troubles, wars, and imperfections, at least as much as our so-called real world.īut their comradeship, began out of necessity, ended decades later unresolved, marred by petty rivalries and burdened by unspoken resentment. Sorrow over their pasts and their retreat from modernity gave them no where to go but their imaginations. ![]() They shared the loss of their parents, which they had both endured as children. They bonded over their harrowing experiences in the trenches of World War I. But their relationship had emotional depth as well. Intellectually, they craved each other’s companionship. Together they helped revise the English syllabus, and for the first time, the Oxford English School created a dialogue between the philology and literature camps. (Tolkien disliked most literature and found little use for any work penned after the medieval era). The two soon became fast friends - even though Lewis had established himself in the literature faction of the English faculty, while Tolkien placed himself firmly on the linguistics and history of languages side. “The unpayable debt that I owe to him was not influence but sheer encouragement,” Tolkien wrote decades later. And in their fledgling efforts as novelists, they served as each others first readers. They both avoided contemporary culture, neither had a car nor would drive one, and both largely ignored politics and the news. Initially Lewis noted some apprehension: In his diary, he wrote of the “smooth, pale, fluent little chap” that there was “no harm in him: only needs a smack or so.”īut the colleagues soon discovered they shared a like-minded interest in languages, poetry, myth and storytelling. Lewis and Tolkien first met in 1926 at a Merton College English Faculty meeting. Lewis attended Oxford, then onward from 1925 taught as a Fellow at the university’s Magdalen College (pronounced “maudlin”) until his departure in 1954. ![]() Aside from spending some retirement years in the suburbs and the seaside town of Bournemouth, Tolkien haunted Oxford nearly his entire adult life.įor three decades, Oxford was also full-time home to Clive Staples Lewis (1898-1963), author of The Chronicles of Narnia and Christian writings like The Screwtape Letters. John Ronald Reuel Tolkien (1892-1973) lived in Oxford on and off for some 50 years: first from 1911-15 as a student, then from 1917-19 as a tutor and staff member of the New English Dictionary, and lastly as a professor of medieval languages and literature from 1925-59. I had come to see the dim pubs where he drank up inspiration and to visit the homes where he scribbled The Lord of the Rings, one of the biggest-selling and most-beloved books of all time.Īlas, I heard the trail was unmarked. Tolkien, the father of modern fantasy, and listen for remnants of his voice. Oxford–I had vowed to take Dead Man’s Walk. 12/15/2023 0 Comments Birds that have there wings cliptBe aware of the bird’s stress level during the process, and take your time and talk calmly to your cockatiel.Make sure to not clip too close to the body of the bird. Trim the feathers evenly on both wings.It is connected to the bird’s skin and it is important not to cut it. It is not necessary to remove all of the feathers from the wings. Only remove a few feathers or the flight feathers at the tips of the wings. Start by trimming the primary feathers, which are the longest feathers along the tips of the wings.It is essential to have a veterinarian or an experienced bird groomer show you how to clip the wings properly in order to avoid any pain or trauma to the bird that can result from an improper trim. It is important to remember that you should never attempt to clip a bird’s wings without the proper instruction, training, and experience. ![]() The best scissors to use to clip a bird’s wings are blunt-edged veterinary scissors, trimmed to the appropriate size. Always sterilize the scissors with rubbing alcohol before and after use. Use sharp scissors or grooming shears to clip the feathers.
12/15/2023 0 Comments Winzip freeThe program is paid and provides a 30 days free trial.īy Rubén Hernández Frequently Asked Questions Is WinZip downloadable for Windows 10? The extensions supported by this program are. Learning how to use the program is simple, thanks to the context-sensitive help that appears when we hover the cursor over any button or menu of the program. Still, as we use it, we will be able to understand all of the functionalities and use them to streamline and improve the compression and decompression process. In the beginning, it is possible that we will not make use of all the options of Winzip. We will have many options to automate certain tasks associated with file compression thanks to Winzip. These plug-ins are paid.Īs we can see, file compression and decompression are simple.
12/15/2023 0 Comments Android civilization v imagesOnline multiplayer is not available on the mobile versions. Q: Does the mobile version have multiplayer?Ī: The Android version of Civilization VI has Local Multiplayer and Play by Cloud. Q: What game modes are available in the Android version?Ī: The Android version of Civilization VI has Single player, Local multiplayer (up to 4 players), and hotseat (up to 6 players on the same device). We will continue to support the existing Android version of Civilization VI and evaluate potential future opportunities, but there are no planned content updates for Android. Q: Is New Frontier Pass content available on Android?Ī: At this time, New Frontier Pass will not be coming to Android devices. Can I transfer my purchases to the Android version?Ī: Purchases on other platforms (iOS, PC, Consoles) are not transferable to the Android version.Ī: The Android version of Civilization VI is a free download and you can play 60 turns for FREE! You can unlock the full base game and all currently released add-ons/expansions up to the Gathering Storm expansion via In-App Purchases.įor a full list of available In-App Purchases, click HERE Q: I already own Civilization VI on another platform. For questions about a specific device, please reach out to us here and we'll help you out. ![]() Q: What languages are supported for the Android version of Civilization VI?Ī: The following languages are supported:Įnglish, French, German, Spanish, Italian, Simplified Chinese, Traditional Chinese, Japanese, Korean, Polish, Russian, Brazilian Portuguese (text-only)Ī: Devices must have at least 4 GB of memory and support Vulkan. ![]() Q: What versions of Android OS are supported?Ī: Android 9 (Pie), Android 10, or Android 11 are required to run Civilization VI. Speaking of performance, there’s now Vulkan 1.3 and initial DirectX 12 support to improve “how shaders are stored and persisted.” Google has improved its “scaling system so you can now performantly play many more games on QHD and UHD displays, and see the performance benefits of reducing in-game resolution on all displays.Below is information on purchasing Civilization VI and its DLCs for Android, minimum requirements for whether your device can run the game, info on multiplayer, and known issues. Meanwhile, when there’s an active game download in the background, devices will no longer sleep. Existing alpha users need to uninstall and reinstall Steam to get these improvements. On the storage management front, ChromeOS has switched to sparse disk and ballooning for games that download content outside of Steam, while this improves file access performance for Proton titles. Power management improvements include showing low battery notifications when playing games in fullscreen, and “reducing CPU overhead in Vulkan and DirectX titles” to extend battery life.
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